Sacrificial Anode-Free Electrosynthesis of α-Hydroxy Acids via Electrocatalytic Coupling of Carbon Dioxide to Aromatic Alcohols
نویسندگان
چکیده
منابع مشابه
Microbial electrosynthesis of butyrate from carbon dioxide.
This work proves for the first time the bioelectrochemical production of butyrate from CO2 as a sole carbon source. The highest concentration of butyrate achieved was 20.2 mMC, with a maximum butyrate production rate of 1.82 mMC d(-1). The electrochemical characterisation demonstrated that the CO2 reduction to butyrate was hydrogen driven. Production of ethanol and butanol was also observed ope...
متن کاملA synthesis of α-amino acids via direct reductive carboxylation of imines with carbon dioxide.
A method for the synthesis of α-amino acids by direct reductive carboxylation of aromatic imines with CO2 is described. The protocol employs readily available commercial reagents and serves as a one-step alternative to the Strecker synthesis.
متن کاملElectrocatalytic oxidation of alcohols by a carbon-supported Rh porphyrin.
A Rh porphyrin on carbon black was shown to catalyze the electro-oxidation of several aliphatic alcohols (ethanol, 1-propanol, and 2-propanol) and benzyl alcohols. The overpotentials for alcohol oxidation were very low. The reaction mechanism and substrate specificity are discussed.
متن کاملSulfonated porous carbon catalyzed esterification of free fatty acids
The esterification of free fatty acids (FFA) with methanol is studied using Sulfonated Porous Carbon (SPC) as catalyst. In compare to the amorphous sugar catalyst and protonated Nafion, the proposed catalyst shows stability and high efficient performance in biodiesel production. The highest initial rate of oleic acid conversion is obtained at catalyst loading of 1 mmol H+ and mole ra...
متن کاملSynthesis of quinazolines via CuO nanoparticles catalyzed aerobic oxidative coupling of aromatic alcohols and amidines.
CuO nanoparticles were found to be efficient catalysts for the synthesis of quinazoline derivatives; twenty-four products were obtained with good to excellent yields via reaction of N-arylamidines and aromatic aldehydes or benzyl alcohol in air. Neither a base nor an organic oxidant was necessary, and CuO nanoparticles can be recycled without a significant decrease in catalytic activity.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: ACS Sustainable Chemistry & Engineering
سال: 2019
ISSN: 2168-0485,2168-0485
DOI: 10.1021/acssuschemeng.9b04612